Metal enrichment to ore grade is the ultimate outgrowth of large-scale and
long-term fractionation processes of the thermally driven and unique water-
cooled geological evolution of the Earth. Silicic magmatism along convergen
t margins is the most important lithospheric fractionation process for the
formation of the continental crust and porphyry/intrusion-related ore depos
its. Reconnaissance microanalysis of melt inclusions from Central Andean po
rphyry systems refines a metallogenic model for copper-gold and tin porphyr
y mineralization. Magmatic mixing and early exsolution of a fluid phase are
important ingredients for porphyry Cu-Au systems in association with silic
ic rocks df moderate levels of fractionation (such as diorites and monzonit
es), whereas extended magmatic fractionation with late-stage fluid evolutio
n characterize lithophile-element-enriched tin porphyry systems.