This research supports recent efforts to provide an energetic approach to t
he prediction of stress-strain relations for single crystals undergoing sin
gle slip and to give precise formulations of experimentally observed connec
tions between hardening of single crystals and separation of active slip-ba
nds. Non-classical, structured deformations in the form of two-level shears
permit the formulation of new measures of the active slip-band separation
and of the number of lattice cells traversed during slip. A formula is obta
ined for the Helmholtz free energy per unit volume as a function of the she
ar without slip, the shear due to slip, and the relative separation of acti
ve slip-bands in a single crystal. This formula is the basis for a model, u
nder preparation by the authors, of hardening of single crystals in single
slip that is consistent with the Portevin-Le Chatelier effect and the exist
ence of a critical resolved shear stress. (C) 2000 Elsevier Science Ltd. Al
l rights reserved.