Coupling reactions between acyl chlorides and Grignard reagents in the presence of a supported Fe(III)-complex

Authors
Dell'Anna, MM Mastrorilli, P Nobile, CF Marchese, G Taurino, MR
Citation
Mm. Dell'Anna et al., Coupling reactions between acyl chlorides and Grignard reagents in the presence of a supported Fe(III)-complex, J MOL CAT A, 161(1-2), 2000, pp. 239-243
Citations number
22
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
ISSN journal
13811169 → ACNP
Volume
161
Issue
1-2
Year of publication
2000
Pages
239 - 243
Database
ISI
SICI code
1381-1169(20001106)161:1-2<239:CRBACA>2.0.ZU;2-Q
Abstract
The polymer-supported Fe(III) complex obtained by copolymerization of Fe(AA EMA)(3) [AAEMA(-) = deprotonated form of 2-(acetoacetoxy) ethyl methacrylat e] with suitable acrylamides facilitates the coupling reaction between acyl chlorides and Grignard reagents, affording ketones with yields up to 96%. (C) 2000 Elsevier Science B.V. All rights reserved.