Edible oils are desterolized in order to render them ''undetectable''
when admixed to other oils. Such frauds remain, however, detectable by
the olefinic degradation products of the sterols: the degradation pro
ducts approximately have the composition of the sterols they originate
from. Presence of campestatriene (degraded brassicasterol) reveals th
e presence of desterolized rapeseed oil. The ratio of the degradation
products of sitosterol and campesterol is a sensitive indicator for de
sterolized -sunflower, soybean, palm, or grapeseed oil in oils of low
campesterol content, such as olive and walnut oil. Analyses were perfo
rmed by on-line coupled LC-GC.