Organic processes initiated by non-classical energy sources

Citation
M. Nuchter et al., Organic processes initiated by non-classical energy sources, J PHYS ORG, 13(10), 2000, pp. 579-586
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF PHYSICAL ORGANIC CHEMISTRY
ISSN journal
08943230 → ACNP
Volume
13
Issue
10
Year of publication
2000
Pages
579 - 586
Database
ISI
SICI code
0894-3230(200010)13:10<579:OPIBNE>2.0.ZU;2-1
Abstract
Non-classical energy sources such as microwave energy, ultrasound and mecha noenergy and their combination with UV-VIS radiation are new tools in synth etic chemistry and chemical processing. Here we describe the application of microwave treatment for selected organic reactions such as (i) enzymatic t ransesterification of opticially active alcohols, (ii) mercury-sensitized g as-phase photolysis of hydrocarbons in the microwave field, (iii) environme ntally benign oxidations of olefins and (iv) the application of mechanoener gy separately and in combination with microwave irradiation for special oxi dation reactions. Copyright (C) 2000 John Wiley & Sons, Ltd.