Evaluation of the chemical exergy of fuels and petroleum fractions

Authors
Govin, OV Diky, VV Kabo, GJ Blokhin, AV
Citation
Ov. Govin et al., Evaluation of the chemical exergy of fuels and petroleum fractions, J THERM ANA, 62(1), 2000, pp. 123-133
Citations number
9
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
ISSN journal
13886150 → ACNP
Volume
62
Issue
1
Year of publication
2000
Pages
123 - 133
Database
ISI
SICI code
1388-6150(2000)62:1<123:EOTCEO>2.0.ZU;2-E
Abstract
A correlation formula to estimate chemical exergies of oil fractions and fu el mixtures from enthalpy of combustion and atomic composition is developed . Heat capacity of a mixture of 10 hydrocarbons was measured in the range 5 -290 K. It was shown that contribution of entropy of mixing to exergy of ty pical oil fractions is about -0.11% in the approximation of ideal solution, and about -0.18% for a real solution.