Electronic transport and thermal and optical properties of Ca1-xLaxB6

We present a study of transport, thermal, and optical properties of stoichi ometric CaB6 and La-doped CaB6. For stoichiometric CaB6 a strong increase o f;the resistivity with decreasing temperature and anomalies in the low-temp erature behavior of the resistivity and the specific heat have been observe d. The application of an external magnetic field at low temperatures is sho wn to lead to an anomalous magnetoresistance in the case of stoichiometric CaB6. The optical conductivity exhibits a strong doping dependence. Rather unexpectedly, small changes in the chemical composition lead to significant changes in the electronic interband transitions in the visible-UV spectral range. The relevance of our results with respect to the recently suggested excitonic scenario for explaining the physical properties of alkaline-eart h hexaborides is discussed.