S. Ishihara et S. Maekawa, Theory of orbital ordering, fluctuation, and resonant x-ray scattering in manganites, PHYS REV B, 62(14), 2000, pp. R9252-R9255
We present a theoretical framework of resonant x-ray scattering (RXS) to st
udy orbital order-disorder phase transition in manganites. The scattering c
ross section (SCS) of RXS is given by the correlation function of the pseud
ospin operator for the orbital degree of freedom in Mn ions. The order para
meter, critical fluctuation, and their critical exponents in the phase tran
sition are studied like those of spin and charge done in neutron and x-ray
scatterings, respectively. The temperature, momentum, and polarization depe
ndences of the SCS are calculated independently of detailed scattering proc
esses. The theory may also be applied to RXS in other compounds with an orb
ital degree of freedom.