Coupling between tilt and polar orders in liquid crystal phases formed from achiral bent shaped molecules

Citation
P. Toledano et al., Coupling between tilt and polar orders in liquid crystal phases formed from achiral bent shaped molecules, PHYS REV E, 62(4), 2000, pp. 5143-5153
Citations number
27
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW E
ISSN journal
1063651X → ACNP
Volume
62
Issue
4
Year of publication
2000
Part
A
Pages
5143 - 5153
Database
ISI
SICI code
1063-651X(200010)62:4<5143:CBTAPO>2.0.ZU;2-N
Abstract
A phenomenological description is given of the mesophases which may arise b elow a liquid formed from achiral molecules possessing a transverse dipole, as the result of a coupling between their tilt and polar orders. Six stabl e mesophases are found. Two of them have a cholesteric biaxial structure. T he others display antiferroelectric or ferrielectric, incommensurately modu lated, structures with in-plane or out-of-plane spontaneous polarization. T he in-plane polarized structures become unstable under application of a lon gitudinal electric field. Other field-induced effects are discussed.