A device for on-line electromigration measurements of radioelements in free electrolytes

Citation
E. Mauerhofer et al., A device for on-line electromigration measurements of radioelements in free electrolytes, RADIOCH ACT, 88(7), 2000, pp. 399-404
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RADIOCHIMICA ACTA
ISSN journal
00338230 → ACNP
Volume
88
Issue
7
Year of publication
2000
Pages
399 - 404
Database
ISI
SICI code
0033-8230(2000)88:7<399:ADFOEM>2.0.ZU;2-I
Abstract
An electromigration device has been developed for the on-line measurement o f absolute individual ion mobilities of radioactive species in free electro lytes. The device is composed of a migration cell, a gamma -radiation scann ing unit and a data processing system. The performance of two BGO-scintilla tors as scanning unit and the reliability of an on-line data processing sys tem were studied with calibrated radioactive sources of given velocities. T he system was found to work with a high reproducibility rate. The migration velocities were determined with an accuracy better than 1%.