An electromigration device has been developed for the on-line measurement o
f absolute individual ion mobilities of radioactive species in free electro
lytes. The device is composed of a migration cell, a gamma -radiation scann
ing unit and a data processing system. The performance of two BGO-scintilla
tors as scanning unit and the reliability of an on-line data processing sys
tem were studied with calibrated radioactive sources of given velocities. T
he system was found to work with a high reproducibility rate. The migration
velocities were determined with an accuracy better than 1%.