Solid platinum superoxo hydroxo complex

Authors
Pankratov, DA Komozin, PN Kiselev, YM
Citation
Da. Pankratov et al., Solid platinum superoxo hydroxo complex, RUSS J IN C, 45(10), 2000, pp. 1555-1559
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
00360236 → ACNP
Volume
45
Issue
10
Year of publication
2000
Pages
1555 - 1559
Database
ISI
SICI code
0036-0236(200010)45:10<1555:SPSHC>2.0.ZU;2-4
Abstract
Solid samples isolated from solutions of a platinum superoxo hydroxo comple x are studied by EPR and X-ray powder diffraction techniques. The short-liv ed superoxo complex is found to form upon dissolution of the solid samples in concentrated acids. Magnetic resonance parameters of the platinum supero xo complexes in the solid state and in acidic solutions are determined. The structures of the inner coordination sphere of the found superoxo complexe s are discussed.