Alkylation of phenol and its derivatives with camphene on large-porous beta-zeolite

Authors
Fomenko, VV Korchagina, DV Salakhutdinov, NF Bagryanskaya, IY Gatilov, YV Ione, KG Barkhash, VA
Citation
Vv. Fomenko et al., Alkylation of phenol and its derivatives with camphene on large-porous beta-zeolite, RUSS J ORG, 36(4), 2000, pp. 539-552
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
10704280 → ACNP
Volume
36
Issue
4
Year of publication
2000
Pages
539 - 552
Database
ISI
SICI code
1070-4280(200004)36:4<539:AOPAID>2.0.ZU;2-S
Abstract
Alkylation of phenol, anisole, and their methyl-substituted derivative with camphene catalyzed by large-porous beta-zeolite yielded the corresponding terpenylphenols, terpenylanisoles, and terpenyl phenyl ethers. C- or O-alky iation occurs depending on phenol structure and on the solvent used. At C-a lkylation the main reaction product has uncommon structure of the terpene r est with methyl groups in 1, 4,and 7 positions.