During recent years diluted magnetic semiconductors based on III-V compound
s have been of considerable interest. In this respect we review the basic p
roperties of these materials, which are nearly exclusively Mn-based systems
, such as GaMnAs, InMnAs, GaMnSb, and GaN:Mn. We discuss the nature of Mn i
mpurity. Different Mn centers are considered and experimental pieces of evi
dence suggesting the dominating role of Mn (d(5)) configuration are given.
Then we analyze s, p-d exchange, together with resulting magnetooptical pro
perties tin particular absorption edge slitting for heavily p-type GaMnAs).
The coupling between Mn ions (d-d exchange) and ferromagnetic ordering obs
erved in InMnAs and GaMnAs is the next subject. Some mechanisms responsible
for this ordering ale presented. Finally we discuss transport properties a
nd some selected problems of quantum structures based on III-V diluted magn
etic semiconductors.