Deactivation of a [PPN][Rh(CO)(4)]-based catalytic system [PPN+ = (PPh3)(2)N+]. The first decomposition reaction of PPN+ and the formation of [Rh10P(CO)(22)](3-)

Authors
Ragaini, F Sironi, A Fumagalli, A
Citation
F. Ragaini et al., Deactivation of a [PPN][Rh(CO)(4)]-based catalytic system [PPN+ = (PPh3)(2)N+]. The first decomposition reaction of PPN+ and the formation of [Rh10P(CO)(22)](3-), CHEM COMMUN, (21), 2000, pp. 2117-2118
Citations number
12
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
21
Year of publication
2000
Pages
2117 - 2118
Database
ISI
SICI code
1359-7345(2000):21<2117:DOA[CS>2.0.ZU;2-O
Abstract
Decomposition of [PPN][Rh(CO)(4)] [PPN+ = (PPh3)(2)N+] at 200 degreesC unde r CO pressure affords [Rh10P(CO)(22)](3-), featuring the first decompositio n reaction of PPN+ and explaining the reason for the deactivation of [PPN][ Rh(CO)(4)]-based catalytic systems.