Hydrothermal synthesis and crystal structures of two novel hybrid open-frameworks and a two-dimensional network based on tungsten(VI) oxides

Authors
Yan, BB Xu, Y Goh, NK Chia, LS
Citation
Bb. Yan et al., Hydrothermal synthesis and crystal structures of two novel hybrid open-frameworks and a two-dimensional network based on tungsten(VI) oxides, CHEM COMMUN, (21), 2000, pp. 2169-2170
Citations number
21
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
21
Year of publication
2000
Pages
2169 - 2170
Database
ISI
SICI code
1359-7345(2000):21<2169:HSACSO>2.0.ZU;2-P
Abstract
Three new tungsten(VI) oxide hybrid materials, [WO3(pyz)(0.5)] (pyz=pyrazin e) 1, [WO3(bpy)(0.5)] (bpy = 4,4'-bipyridyl) 2 and [W3O10(enH(2))] 3, have been hydrothermally synthesized: 1 and 2 exhibit covalent/coordination hybr id framework connectivities while the structure of 3 consists of novel laye rs comprised of distorted {WO6} octahedra linked through edge- and corner-s haring interactions.