DIOXOMOLYBDENUM(VI) COMPLEXES OF BIDENTATE AND TETRADENTATE SCHIFF-BASES DERIVED FROM 3-METHYL-1-PHENYL-4-PROPIONYL-2-PYRAZOLIN-5-ONE AND CERTAIN AROMATIC-AMINES
Rc. Maurya et al., DIOXOMOLYBDENUM(VI) COMPLEXES OF BIDENTATE AND TETRADENTATE SCHIFF-BASES DERIVED FROM 3-METHYL-1-PHENYL-4-PROPIONYL-2-PYRAZOLIN-5-ONE AND CERTAIN AROMATIC-AMINES, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 36(5), 1997, pp. 406-410
The synthesis of some cis-dioxomolybdenum(VI) complexes with bidentate
and tetradentate ligands (I & II) derived from 3-methyl-1-phenyl-4-pr
opionyl-2-pyrazolin-5-one and certain aromatic amines are described. T
he complexes are of the type [MoO2(OEt)(L)](2) (where LH=MPHPRP-OAH, M
PHPRP-MAH, MPHPRP-PAH, MPHPRP-OPH, MPHPRP-PPH, MPHPRP-OTH or MPHPRP-MT
H), [MoO2(MPHPRP-OPHD)], and [{MoO2(OEt)}(2)(L)] (where LH2=MPHPRP-MPH
DH2, MPHPRP-PPHDH2 or MPHPRP-BZH(2)). They are characterized by IR, el
ectronic and magnetic studies.