Ccm. Luijten et al., A NEW METHOD FOR DETERMINING BINARY DIFFUSION-COEFFICIENTS IN DILUTE CONDENSABLE VAPORS, International journal of heat and mass transfer, 40(15), 1997, pp. 3497-3502
A new method for determining binary diffusion coefficients in dilute c
ondensable vapors is outlined. The method is based on condensational d
roplet growth. It can be used in a large range of pressures and temper
atures, even below the Freezing point of the condensing vapor. Results
are obtained for the mixtures water-nitrogen and water-helium in the
pressure range 11-44 bar. The product of pressure and diffusivity is f
ound to be constant. New temperature correlations for the binary diffu
sion coefficient are proposed, valid for the range 235-375 K. For wate
r-nitrogen the temperature dependence is significantly stronger than p
redicted by the Fuller correlation; for water-helium, it is weaker. (C
) 1997 Elsevier Science Ltd.