Reactivity of schiff base, Part-4: Reaction of 2-/4-hydroxybenzylidene-2-aminobenzothiazole with aniline in microemulsion

Citation
Bk. Mishra et al., Reactivity of schiff base, Part-4: Reaction of 2-/4-hydroxybenzylidene-2-aminobenzothiazole with aniline in microemulsion, I J CHEM A, 39(7), 2000, pp. 721-727
Citations number
24
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
39
Issue
7
Year of publication
2000
Pages
721 - 727
Database
ISI
SICI code
0376-4710(200007)39:7<721:ROSBPR>2.0.ZU;2-E
Abstract
Nucleophilic reaction at azomethine center of 2-/4-hydroxybenzylidene-2-ami nobenzothiozole by aniline has been investigated in sodium lauryl sulphate( NaLS) - isobutanol-chloroform-water microemulsion media. The role of hydrox y group at ortho and para positions in the benzene nucleus on the reaction mechanism has been analyzed. The entrapment of aniline by the reacting subs trate gets support from the reaction kinetics.