The pillared montmorillonite has been prepared by exchanging Na+ in the int
erlayer of montmorillonite with Al hydroxy cation followed by calcination.
Pillared clays are also prepared after exchanging Na+ ions with Cc, La, Sm-
ions and then pillared with aluminium oxides. The surface characterisation
of the prepared catalysts has been done using XRD and surface area measurem
ents. To probe the acidic property of the system, temperature programmed de
sorption (TPD) of NH3 has been done. Toluene alkylation by benzyl chloride
has been carried out for the evaluation of catalytic activity. The most act
ive system is found to be mixed Al/Zr pillared montmorillonite.