Improved syntheses of cyanuric fluoride and carboxylic acid fluorides

Authors
Gross, S Laabs, S Scherrmann, A Sudau, A Zhang, N Nubbemeyer, U
Citation
S. Gross et al., Improved syntheses of cyanuric fluoride and carboxylic acid fluorides, J PRAK CHEM, 342(7), 2000, pp. 711-714
Citations number
27
Categorie Soggetti
Chemistry
Journal title
JOURNAL FUR PRAKTISCHE CHEMIE-PRACTICAL APPLICATIONS AND APPLIED CHEMISTRY
ISSN journal
14369966 → ACNP
Volume
342
Issue
7
Year of publication
2000
Pages
711 - 714
Database
ISI
SICI code
1436-9966(2000)342:7<711:ISOCFA>2.0.ZU;2-X
Abstract
Cyanuric fluoride (2) is one of the most popular fluorinating agents in org anic chemistry. The title compound could be prepared in a 50 to 100 g scale by means of a chlorine fluorine exchange, the process was characterized by a simple preparation procedure, cheap reactants and a low time exposure. C arboxylic acids were converted into the corresponding acid fluorides 4a-g u sing cyanuric fluoride. A nonaqueous work-up led to high yields on synthesi zing a range of functionalized acid fluorides.