Thermogravimetric measurement of hydrogen absorption in alkali-modified carbon materials

We have prepared Li-doped multiwall carbon nanotubes and Li- and K-intercal ated graphite and measured their hydrogen storage properties using a thermo gravimetric analyzer (TCA). In a flowing 1-12 atmosphere Li-doped nanotubes and Li-intercalated graphite both exhibit a cyclable weight gain between 2 00 and 300 degreesC and weight loss between 400 and 500 degreesC characteri zed by a distinct and unusual temperature profile. We find, however, that n either H-2 nor carbon is required to generate this TGA feature; we observe it even in Li-containing samples measured in flowing Ar without H-2 and in LiOH samples measured in either Wt or Ar. Potassium-intercalated graphite s hows mass cycling with a different thermal character between 40 and 250 deg reesC, but as with H-2, observation of a large cyclable feature does not re ly on the presence of H-2 In both cases we identify the cycling mass to be absorption/desorption of H2O present as an impurity in the TGA atmosphere. The temperature signatures we observe are strikingly similar to those repor ted in a recent study of Li- and K-doped carbon nanofibers in which mass up takes as large as 20 wt% were attributed to hydrogen absorption. When the i mpurities in the TGA atmosphere are reduced as much as possible we do detec t modest weight changes in K-intercalated graphite which we interpret as tr ue hydrogen absorption at 1.3 wt %, of which 0.2 wt % is cyclable. This lev el of hydrogen absorption is consistent with pressure-composition isotherm measurements on the same material using a gas reaction controller (1.0 wt % total absorption with 0.3 wt % cyclable). We do not detect any evidence of hydrogen absorption by Li-containing carbon materials under our experiment al conditions.