Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

Authors
Banwell, M Hockless, D Jarrott, B Kelly, B Knill, A Longmore, R Simpson, G
Citation
M. Banwell et al., Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide, J CHEM S P1, (21), 2000, pp. 3555-3558
Citations number
33
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1
ISSN journal
14704358 → ACNP
Issue
21
Year of publication
2000
Pages
3555 - 3558
Database
ISI
SICI code
1470-4358(2000):21<3555:CATTDC>2.0.ZU;2-G
Abstract
The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-Alder cycloaddition reactions with maleic and cit raconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring syste m associated with spinosyns A (1) and D (2).