A comparison of H-2 and Xe-129 NMR as a probe of the effect of crosslinking in rubbery materials

Authors
Menge, H Kuhn, H Blumich, B Blumler, P Schneider, H
Citation
H. Menge et al., A comparison of H-2 and Xe-129 NMR as a probe of the effect of crosslinking in rubbery materials, MACRO MAT E, 282(9), 2000, pp. 1-4
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR MATERIALS AND ENGINEERING
ISSN journal
14387492 → ACNP
Volume
282
Issue
9
Year of publication
2000
Pages
1 - 4
Database
ISI
SICI code
1438-7492(200010)282:9<1:ACOHAX>2.0.ZU;2-S
Abstract
Communication: This paper describes the investigation of butadiene rubber n etworks varying in crosslink density by means of xenon (Xe-129) and deutero n (H-2) NMR spectroscopy. Xe-129 NMR spectra give an evidence of structural inhomogeneities inside the lower crosslinked network which were already ob served in previous deuteron NMR studies under uniaxial deformation. The res ults are discussed in comparison with theoretical models and simulations. I t appears that experiment, theory and also simulation are: now coming toget her to give a detailed picture of the behaviour of these rubbery materials.