A. Voigt et al., Preparation of microcapsules of strong polyelectrolyte couples by one-stepcomplex surface precipitation, MACRO MAT E, 282(9), 2000, pp. 13-16
Full Paper: Polyelectrolyte microcapsules are fabricated by a one-step surf
ace precipitation and by a layer-by-layer technique an decomposable colloid
s. The ternary solvent water/acetone/sodium bromide is adjusted properly ke
eping dissolved simultaneously the strong polyelectrolytes sodium poly(styr
ene sulfonate) and poly(vinyl benzyl trimethylammonium chloride). Microcaps
ules are characterized by confocal laser scanning microscopy and scanning f
orce microscopy. The capsules are dissolvable in the ternary solvent. Other
dissolved strong polyelectrolyte couples and template-free preparation pat
hways are suggested.