P. Reb et al., Polymerizable and nonpolymerizable isophthalic acid derivatives as surfactants in emulsion polymerization, MACROMOLEC, 33(21), 2000, pp. 7718-7723
This article presents an initial study on the use of polymerizable and nonp
olymerizable isophthalic acid derivatives as novel emulsifiers in emulsion
polymerization. The polymerization process and the final latex properties a
re compared to latices made under the same conditions with commercial surfa
ctants: sodium dodecyl sulfate (SDS) and potassium pentadecanoate (C15A). T
he use of the difunctional isophthalic acid appears to increase the stabili
ty of the polymer dispersion. This stabilization effect was further improve
d by introducing polymerizable derivatives. This kind of emulsion polymeriz
ation process is a new way of creating functional nanoparticles.