Permittivity dispersion and transient current profiles of two classes of li
quid crystal substances were analyzed, providing an idea of probable mechan
isms of ion generation. Due to the strong local field caused by the electri
c double layers by ions, Schottky injection at electrodes can play an impor
tant role even under a small DC voltage application. In a higher voltage re
gion, the dissociation of ion pairs and the recombination of free ions can
be the dominant mechanisms, resulting in the Ohmic behavior of the voltage
dependence of a steady-state current. Understandings of those mechanisms wi
ll be of a great help for development of advanced liquid crystal materials
for uses in sophisticated displays.