Synthesis and characterization of tantalum silyl and disilyl imido complexes that do not contain anionic pi-ligands

Authors
Wu, ZZ Xue, ZL
Citation
Zz. Wu et Zl. Xue, Synthesis and characterization of tantalum silyl and disilyl imido complexes that do not contain anionic pi-ligands, ORGANOMETAL, 19(21), 2000, pp. 4191-4192
Citations number
53
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
21
Year of publication
2000
Pages
4191 - 4192
Database
ISI
SICI code
0276-7333(20001016)19:21<4191:SACOTS>2.0.ZU;2-V
Abstract
Tantalum disilyl and silyl complexes [(Me3Si)(2)N](Me3SiN=)Ta(SiPh2But)(2) (1) and [(Me3Si)(2)N](Me2N)(Me3SiN=)Ta(SiPh2But) (2) have been prepared and characterized. They are; to our knowledge, the first known cyclopentadieny l-free group 5 imido disilyl and silyl complexes.