Palladium-catalyzed hydrophosphorylation of allenes leading to regio- and stereoselective formation of allylphosphonates

Authors
Zhao, CQ Han, LB Tanaka, M
Citation
Cq. Zhao et al., Palladium-catalyzed hydrophosphorylation of allenes leading to regio- and stereoselective formation of allylphosphonates, ORGANOMETAL, 19(21), 2000, pp. 4196-4198
Citations number
33
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
21
Year of publication
2000
Pages
4196 - 4198
Database
ISI
SICI code
0276-7333(20001016)19:21<4196:PHOALT>2.0.ZU;2-6
Abstract
Palladium 1,1'-bis(diphenylphosphino)ferrocene complex catalysts promote th e addition of HP(O)(OCMe2CMe2O), to terminal allenes to afford the correspo nding 1,2-adducts regio- and stereoselectively in high yields.