A new model of porous-silicon (PS) luminescence based on hot-electron gener
ation in silicon nanoparticles is proposed. This mechanism was used earlier
for interpretation of light emission in island metal films (IMF). This pap
er offers a theoretical analysis of possible mechanisms capable of producin
g light emission in hot-electron collisions with a surface. Experimental da
ta are presented in support of the applicability of this model to PS and si
licon nanoparticles (the existence of electron emission in semiconductor st
ructures and the correlation between the electron emission current and the
luminescence intensity). (C) 2000 MAIK "Nauka/Interperiodica".