R. Jantas et Z. Draczynski, Kinetics of addition of diethylamine to oligo[(2-acryloyloxy-5-methyl-1,3-phenylene)-methylene] catalyzed by lithium diethylamide, REACT KIN C, 70(2), 2000, pp. 251-257
The kinetics of addition reaction of diethylamine to vinyl groups of oligo[
(2-acryloyloxy-5-methyl-1,3-phenylene)methylene] in benzene with excess ami
ne in the presence of lithium diethylamide as catalyst has been investigate
d. The reaction rate, was found to be expressed as: V = k [CH2=CH-][Et2NLi]
with the ratio of [Et2NH]o to [Et2NLi]o being 5. Second-order rate constan
ts for addition and the activation energy have been determined.