Methane aromatization in the absence of oxygen over Mo/H[B]ZSM-5 catalysts

Citation
S. Li et al., Methane aromatization in the absence of oxygen over Mo/H[B]ZSM-5 catalysts, REACT KIN C, 70(2), 2000, pp. 349-356
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
REACTION KINETICS AND CATALYSIS LETTERS
ISSN journal
01331736 → ACNP
Volume
70
Issue
2
Year of publication
2000
Pages
349 - 356
Database
ISI
SICI code
0133-1736(200007)70:2<349:MAITAO>2.0.ZU;2-C
Abstract
The catalytic performance of Mo/H[B]ZSM-5 has been investigated for methane non-oxidative aromatization and compared with that of a Mo/H[AI]ZSM-5 cata lyst. It is found that the non-oxidative aromatization of methane proceeds only in the presence of weak acidic sites without the participation of stro ng acidic sites. Coke is found to be the main cause of the rapid decrease i n the activity of Mo/H[B]ZSM-5 catalysts.