Results of a comprehensive study of electrical and photoelectric properties
of isotype (p-Si/p-GaN:O) and anisotype n-Si/p-GaN:O) heterojunctions are
reported. The structures were fabricated by chemical vapor deposition of th
in films of GaN:O solid solutions on silicon substrates by pyrolytic decomp
osition of gallium monoammine chloride in the presence of water vapor. Tota
l and spectral photosensitivity and photoresponse kinetics in the current m
ode under forward and reverse biases, current-voltage characteristics, and
saturation open-circuit photovoltage were studied. It was found that in bot
h kinds of heterojunctions the charge distribution near the contacts is mai
nly governed by carrier capture into interface states (with density estimat
ed to be similar to 10(14)-10(15) cm(-2)) with the formation of depletion l
ayers on both sides of the interface. Photosensitivity mechanisms are analy
zed for anisotype and isotype heterojunctions. It is shown that the differe
ntial nature of the photoresponse kinetics is related to the recharging of
interface states, and the strong rise in the photoresponse signal of a bias
ed anisotype heterojunction is attributed to the phototransistor effect. Th
e proposed energy band models of the heterojunctions consistently describe
the observed effects. (C) 2000 MAIK "Nauka/Interperiodica".