We have studied interdiffusion processes occurring in a metal organic chemi
cal vapour deposition (MOCVD) grown InP/In0.33Ga0.67As/InP/In0.33Ga0.67As/I
nP double quantum well structure through secondary ion mass spectrometry an
d high-resolution x-ray diffraction measurements along with a simulation pr
ogramme. Results show an interdiffusion of phosphorus into the quantum well
s and the presence of a 10 nm thick intermixed zone of In, As and P formed
in-between the cap layer and the subsequent quantum well. Combination of th
ese two techniques along with the simulation is a novel approach towards th
e understanding and quantification of in-depth compositional variation in t
hin films, in general. Copyright (C) 2000 John Wiley & Sons, Ltd.