Dj. Qian et al., Monolayers of a series of viologen derivatives and the electrochemical properties in Langmuir-Blodgett films, THIN SOL FI, 374(1), 2000, pp. 125-133
The effects of a hydrocarbon layer on the electrochemical property of violo
gens were studied by immobilizing a series of symmetrically bis-alkylated v
iologens (CnV, n = 12-18) on an indium-tin oxide electrode surface by using
the Langmuir-Blodgett (LB) method. The electrochemical properties of violo
gen LB films were studied for different parameters; length of alkyl chains,
the nature of counterions in the subphase, and deposition model (X- and Z-
type LB films). Cyclic voltammetric measurements indicated that sr-complex
dimers were easily formed for viologens that had a 'thin' hydrocarbon barri
er (CH2 = 11 and 13) in Z-type LB films, but formed with difficulty for vio
logens that had a 'thick' barrier (CH2 greater than or equal to 15) and for
all viologens in X-type LB films. A weak peak current and a small surface
coverage of 'electroactive' viologens were observed for X-type LB films. Fo
r every viologen-modified In and Sn oxide (ITO) electrode, the reduced pote
ntial was negatively shifted; the thicker the barrier, the larger the shift
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