M. Rontani et Lj. Sham, Thermoelectric properties of junctions between metal and strongly correlated semiconductor, APPL PHYS L, 77(19), 2000, pp. 3033-3035
We propose a junction of metal and rare-earth compound semiconductor as the
basis for a possible efficient low-temperature thermoelectric device. If a
n overlayer of rare-earth atoms differing from the bulk is placed at the in
terface, very high values of the figure of merit ZT can be reached at low t
emperature. This is due to sharp variation of the transmission coefficient
of carriers across the junction at a narrow energy range, which is intrinsi
cally linked to the localized character of the overlayer f orbital. (C) 200
0 American Institute of Physics. [S0003-6951(00)02545-6].