Beneficial effect of cesium salts on Pd-catalyzed hydroxycarbonylation

Authors
Torisawa, Y Nishi, T Minamikawa, J
Citation
Y. Torisawa et al., Beneficial effect of cesium salts on Pd-catalyzed hydroxycarbonylation, BIOORG MED, 10(21), 2000, pp. 2493-2495
Citations number
18
Categorie Soggetti
Chemistry & Analysis
Journal title
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS
ISSN journal
0960894X → ACNP
Volume
10
Issue
21
Year of publication
2000
Pages
2493 - 2495
Database
ISI
SICI code
0960-894X(20001106)10:21<2493:BEOCSO>2.0.ZU;2-0
Abstract
A Pd(0)-catalyzed hydroxycarbonylation of the aryl bromide was effectively carried out in the presence of some Cs salts such as cesium carbonate, cesi um bicarbonate, and cesium acetate in wet DMF solution. For the understandi ng of their function, an oxy-coordinated intermediate arising from a Cs-oxy gen-Pd interaction has been postulated: which is likely to be responsible f or related Cs assisted catalytic processes. (C) 2000 Elsevier Science Ltd. All rights reserved.