Jh. Fan et al., Synthesis and characteristics of new high temperature stationary phase [60] fullerene polysiloxane for capillary gas chromatography, CHEM J CH U, 21(9), 2000, pp. 1359-1363
Two new fullerene-containing polysiloxanes were synthesized by reacting [60
] fullerene with azidepropyl polysiloxane directly and used as the stationa
ry phases for capillary gas chromatography, It demonstrated a high column e
fficiency, wide operational temperature and outstanding thermostability, It
can be used at 360 degreesC with a baseline drift of 3 x 10(-14) similar t
o 4 x 10(-14) nm The stationary phases were especially suitable for separat
ion of high boiling compounds like monosaccharides, polycyclic aromatic hyd
rocarbons and phthalic diesters, etc, It was also found that some alcohols
or aromatic positional isomers can be well separated on the column.