The first total synthesis of (+/-)-sinaiticin

Authors
She, XG Gu, WX Jing, XB Pan, XF
Citation
Xg. She et al., The first total synthesis of (+/-)-sinaiticin, CHEM J CH U, 21(9), 2000, pp. 1395-1398
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
ISSN journal
02510790 → ACNP
Volume
21
Issue
9
Year of publication
2000
Pages
1395 - 1398
Database
ISI
SICI code
0251-0790(200009)21:9<1395:TFTSO(>2.0.ZU;2-I
Abstract
(+/-)-Sinaiticin was first synthesized by nine steps in 13.4% overall yield . In this approach the conversion of cis-6 to trans-7 by epimerization and the oxidative cyclization reaction are the key steps.