The geometrical structures and binding energies of GemSin mixed clusters (s
= m + n less than or equal to 10) have been optimized based upon the nonor
thogonal tight-binding scheme. GemSin mixed clusters are found similar in s
tructures with Si-n and Ge-n (but with lower symmetries) and the binding en
ergies of the mixed clusters are between the corresponding values of the Si
-n and Ge-n.