Zr. Zeng et al., Application of a new stationary phase bonded with macrocyclic dioxopolyamine in open-tubular capillary electrochromatography, CHEM J CH U, 21(9), 2000, pp. 1369-1371
The macrocyclic dioxopolyamine compounds, 1,4, 7, 10-tetraazacyclotridecane
-11,13-diones were used as stationary phases with the aid of 3-(2-cyclooxyp
ropoxyl)propyl-trimethoxy silane as a bridge in open-tubular capillary elec
trochromatography (OTCEC). The capillaries were etched by aqueous sodium be
fore being coated, These modified capillaries had shown improved separation
s of neurotransmitters, isomeric dihydrobenzenes, isomeric nitrophenols and
isomeric aminophenols in comparison with untreated capillaries.