Application of time-temperature superposition principle to evaluation of scattering intensity evolution in phase separation for PMMA/SAN blends

Authors
Peng, M Zheng, Q
Citation
M. Peng et Q. Zheng, Application of time-temperature superposition principle to evaluation of scattering intensity evolution in phase separation for PMMA/SAN blends, CHIN J POLY, 18(6), 2000, pp. 565-568
Citations number
5
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
CHINESE JOURNAL OF POLYMER SCIENCE
ISSN journal
02567679 → ACNP
Volume
18
Issue
6
Year of publication
2000
Pages
565 - 568
Database
ISI
SICI code
0256-7679(200011)18:6<565:AOTSPT>2.0.ZU;2-S
Abstract
Spinodal phase separation behavior of poly(methyl methacrylate)/poly(styren e-co-acrylonitrile) (PMMA/SAN) blends was investigated by the time-resolved small angle light scattering (SALS) technique. It was found that the influ ence of temperature on the scattering intensity evolution followed the time -temperature superposition principle. The relationship between temperature and the relaxation ti me of scattering intensity I(t) can be well described by the Williams-Landel-Ferry (WLF) function.