Transition from calc-alkaline to potassium-rich magmatism in subduction environments: geochemical and Sr, Nd, Pb isotopic constraints from the islandof Vulcano (Aeolian arc)
G. De Astis et al., Transition from calc-alkaline to potassium-rich magmatism in subduction environments: geochemical and Sr, Nd, Pb isotopic constraints from the islandof Vulcano (Aeolian arc), CONTR MIN P, 139(6), 2000, pp. 684-703
The problem of mantle metasomatism vs. crustal contamination in the genesis
of are magmas with different potassium contents has been investigated usin
g new trace element and Sr-Nd-Pb isotopic data on the island of Vulcano, Ae
olian are. The analysed rocks range in age from 120 ka to the present day,
and cover a compositional range from basalt to rhyolite of the high-K calc-
alkaline (HKCA) to shoshonitic (SKO) and potassic (KS) series. Older Vulcan
o products (> 30 ka) consist of HKCA-SHO rocks with SiO2 = 48-56%. They sho
w lower contents of K2O, Rb and of several other incompatible trace element
abundances and ratios than younger rocks with comparable degree of evoluti
on. Sr-87/Sr-86 ranges from 0.70417 to 0.70504 and increases with decreasin
g MgO and compatible element contents. Pb-206/Pb-204 ratios display signifi
cant variations (19.31 to 19.76) and are positively correlated with MgO, Nd
-143/Nd-144 (0.512532-0.512768), Pb-207/Pb-204 (15.66-15.71) and Pb-208/Pb-
204 (39.21-39.49). Overall, geochemical and isotopic data suggest that the
evolution of the older series was dominated by assimilation-fractional crys
tallisation (AFC) with an important role for continuous mixing with mafic l
iquids. Magmas erupted within the last 30 ka consist mostly of SHO and KS i
ntermediate and acid rocks, with minor mafic products. Except for a few aci
d rocks, they display moderate isotopic variations (e.g. Sr-87/Sr-86, 0.704
57-0.70484; Pb-206/Pb-204 = 29.28-19.55, but Pb-207/Pb-204 = 15.66-15.82),
which suggest an evolution by fractional crystallisation, or in some cases
by mixing, with little interaction with crustal material. The higher Sr iso
topic ratios (Sr-87/Sr-86 = 0.70494-0.70587) of a few, low-volume, intermed
iate to acid rocks support differentiation by AFC at shallow depths for som
e magma batches. New radiogenic isotope data on the Aeolian islands of Alic
udi and Stromboli, as well as new data for lamproites from central Italy, a
re also reported in order to discuss along-are compositional variations and
to evaluate the role of mantle metasomsatism. Geochemical and petrological
data demonstrate that the younger K-rich mafic magmas from Vulcano cannot
be related to the older HKCA and SHO ones by intra-crustal evolutionary pro
cesses and point to a derivation from different mantle sources. The data fr
om Alicudi and Stromboli suggest that, even though interaction between magm
a and wall rocks of the Calabrian basement during shallow level magma evolu
tion was an important process locally, a similar interpretation can be exte
nded to the entire Aeolian are.