Synthesis, characterization and reactions of novel cycloketones C6H2(CH2)(4)(CO)(2) and C-6(CH2)(6)(CO)(3)

Authors
Ullah, SS Alam, FR Haque, MR
Citation
Ss. Ullah et al., Synthesis, characterization and reactions of novel cycloketones C6H2(CH2)(4)(CO)(2) and C-6(CH2)(6)(CO)(3), I J CHEM B, 39(7), 2000, pp. 539-541
Citations number
8
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION B-ORGANIC CHEMISTRY INCLUDING MEDICINAL CHEMISTRY
ISSN journal
03764699 → ACNP
Volume
39
Issue
7
Year of publication
2000
Pages
539 - 541
Database
ISI
SICI code
0376-4699(200007)39:7<539:SCARON>2.0.ZU;2-S
Abstract
Reactions of AlCl3 with 2,3,5,6-tetramethylenebicyclo[2.2.0]hexanediironhex acarbonyl 3 and 1,2,3,4,5,6-hexamethylenecyclohexanenonacarbonyltriiron 5 i n refluxing THF yield cycloketones [C6H2(CH2)(4)(CO)(2)] 4 and [C-6(CH2)(6) (CO)(3)] 6 respectively. The novel cycloketones 4 and 6 alo ng with 2,4-din itrophenylhydrazine derivative of the 4 have been characterized by IR, H-1 NMR and mass spectra.