The microwave dielectric properties of (Pb0.4Ca0.6){(Mg1/3Nb2/3)(1-x)Sn-x}O
-3 (0 less than or equal to x less than or equal to 0.1) ceramics have been
investigated. The (Pb0.4Ca0.6)(Mg1/3Nb2/3)O-3 ceramic was tetragonal compl
ex perovskite single phase material and single phase specimens having tetra
gonal complex perovskite could also be obtained in case of substituting by
tin(Sn). The partial substitution of [Mg1/3Nb2/3](4+) by Sn4+ at B-site of
the perovskite structure significantly improves the loss quality factor (Q)
and slightly decreases dielectric constant (epsilon (r)) and temperature c
oefficient of resonant frequency (tau (f)). The temperature coefficient of
resonant frequency of 0 ppm/degreesC was realized at x = 0.01. The Q.f(o) v
alue and epsilon (r) for this composition were found to be 7130 GHz and 64.
7 respectively.