Plasma was formed on the surface of an electrode in a liquid solution when
metal cathodes underwent high-voltage electrolysis. A red-time heat calibra
tion system was designed for detecting the amount of heat generated during
plasma electrolysis. The measured heat exceeded the input power substantial
ly, and in some cases 200% of the input power. The heat generation process
depended on the conditions for electrolysis. There was no excess heat at th
e beginning of plasma electrolysis. However, after plasma electrolysis for
a long time, a large amount of heat was generated. The reproducibility woul
d be 100% if all factors such as temperature, voltage and duration were opt
imized. Based on the heat and the products, we hypothesize that some unique
reaction occurs on the cathode surface. This reaction may not occur at ene
rgy levels available during electrochemical electrolysis.