Ion velocities in vacuum arc plasmas have been measured for most conducting
elements of the Periodic Table. The method is based on drift time measurem
ents via the delay time between arc current modulation and ion flux modulat
ion. A correlation has been found between the element-specific ion velocity
and average ion charge state; however, differently charged ions of the sam
e element have approximately the same velocity. These findings contradict t
he potential hump model but are in agreement with a gasdynamic model that d
escribes ion acceleration as driven by pressure gradients and electron-ion
friction. The differences between elements can be explained by the element-
specific power density of the cathode spot plasma which in turn determines
the temperature, average charge state, and ion velocity of the expanding va
cuum arc plasma. (C) 2000 American Institute of Physics. [S0021-8979(00)087
23-5].