Synthesis of AA-based superabsorbent interpenetrated with sodium PVA sulfate

An interpenetrating network of acrylic acid (AA)-based superabsorbents and sodium PVA sulfate (SPS) were prepared by copolymerizing AA and N,N'-methyl ene bisacrylamide as a crosslinking monomer in a solution of SPS with KPS, a radical initiator. The SPS was prepared through the sulfation of the hydr oxyl groups of PVA with DMF-SO3 complex in DMSO. The AA-based superabsorben t interpenetrated with SPS (SA-IP-SPS) showed superior properties such as h igher water and saline absor bency, absorbency under load (AVL), and water retention value (WRV) compared with AA-based superabsorbent due to the inte rpenetrated SPS. The maximum water and saline absorbency of SA-IP-SPS was 1 753 and 125.6 g/g, respectively. (C) 2000 John Wiley & Sons, Inc.