A Gibbs ensemble Monte Carlo study of phase coexistence in the solvent primitive model

The phase coexistence behavior of the solvent primitive model (SPM) is stud ied by constant pressure and temperature Gibbs ensemble Monte Carlo simulat ions. In the SPM, the ions are modeled with charged hard spheres, while the solvent molecules are represented by neutral hard spheres. Fluid-fluid pha se separation into a salt poor and salt rich phase is found. At constant pr essure, the critical temperature increases with respect to the critical tem perature of the primitive model (PM) where no hard spheres are present. At constant temperature and for low pressures, the phase separation of the SPM transforms into the phase separation of the PM. For high pressures, it rem ains an open question whether there is an upper critical immiscibility pres sure or whether a solid-fluid phase transition occurs first. (C) 2000 Ameri can Institute of Physics. [S0021-9606(00)52541-0].