Three novel nonlinear parameter estimators are devised and implemented for
accurate and fast processing of experimentally measured or theoretically ge
nerated time signals of arbitrary length. The new techniques can also be us
ed as powerful tools for diagonalization of large matrices that are customa
rily encountered in quantum chemistry and elsewhere. The key to the success
and the common denominator of the proposed methods is a considerably reduc
ed dimensionality of the original data matrix. This is achieved in a prepro
cessing stage called beamspace windowing or band-limited decimation. The me
thods are decimated signal diagonalization (DSD), decimated linear predicto
r (DLP), and decimated Pade approximant (DPA). Their mutual equivalence is
shown for the signals that are modeled by a linear combination of time-depe
ndent damped exponentials with stationary amplitudes. The ability to obtain
all the peak parameters first and construct the required spectra afterward
s enables the present methods to phase correct the absorption mode. Additio
nally, a new noise reduction technique, based upon the stabilization method
from resonance scattering theory, is proposed. The results obtained using
both synthesized and experimental time signals show that DSD/DLP/DPA exhibi
t an enhanced resolution power relative to the standard fast Fourier transf
orm. Of the three methods, DPA is found to be the most efficient computatio
nally. (C) 2000 American Institute of Physics. [S0021-9606(00)00440-2].