This paper describes a simple model for state resolved associative desorpti
on, and by assuming detailed balance, of activated dissociative chemisorpti
on. The equations that result from this model are identical to those tradit
ionally used empirically in fits to experimental data. This allows better u
nderstanding of parameters used to fit experiments and how to compare these
with theory. The role of model parameters in describing activated dissocia
tion when the barrier is almost exclusively along a vibrational coordinate
is also examined. (C) 2000 American Institute of Physics. [S0021-9606(00)70
740-9].